Prof. Gerald Dyker - VideoVorlesungen
Videokanal der RUB: www.youtube.com/user/ChemieRUB
Organic Synthesis I: Stoechiometric Organometallics
Wintersemester 2013/14
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Lecture Stoechiometric Organometallics 1
- Pearsons HSAB principle 15.10.2013 -
Lecture Stoechiometric Organometallics 2
- General scheme for the synthesis of organometallics; methods of metal activation 16.10.2013 -
Lecture Stoechiometric Organometallics 3
- Selectivity in halogen-metal exchange and transmetalation 22.10.2013 -
Lecture Stoechiometric Organometallics 4
- The endocyclic restriction test; mechanism of halogen-metal exchange by permutational interconversion 23.10.2013 -
Lecture Stoechiometric Organometallics 5
- DOM reactions: Directed ortho-metalation 29.10.2013 -
Lecture Stoechiometric Organometallics 6
- Organometallic Superbases 30.10.2013 -
Lecture Stoechiometric Organometallics 7
- Regioselective Deprotonation of Carbonyl Compounds 05.11.2013 -
Lecture Stoechiometric Organometallics 8
- Enantioselective Deprotonation 06.11.2013 -
Lecture Stoechiometric Organometallics 9
- Diastereoselectivity at Carbonyl Reduction, Felkin-Anh Model 12.11.2013 -
Lecture Stoechiometric Organometallics 10
- Ireland-Claisen Rearrangement 13.11.2013 -
Lecture Stoechiometric Organometallics 11
- Diastereoselectivity of Aldol Addition Reactions; Zimmerman-Traxler Transition States 19.11.2013 -
Lecture Stoechiometric Organometallics 12
- Metal-specific features: Magnesium – Grignard or Barbier? 20.11.2013 -
Lecture Stoechiometric Organometallics 13
- Metal-specific features: Magnesium – Magnesium-Ene Reaction 26.11.2013 -
Lecture Stoechiometric Organometallics 14
- Metal-specific features: Cerium in Organic Synthesis, Copper: Organocuprates 27.11.2013 -
Lecture Stoechiometric Organometallics 15
- Metal-specific features: Cuprates in Organic Synthesis, conjugate addition reactions, crossed Wurtz coupling, Glaser coupling reaction 02.12.2013 -
Lecture Stoechiometric Organometallics 16
- Metal-specific features: Zinc, Reformatski reaction, Nozaki olefination, Simmons-Smith cyclopropanation 03.12.2013 -
Lecture Stoechiometric Organometallics 17
- Metal-specific features: Boron, applications of hydroboration 10.12.2013 -
Lecture Stoechiometric Organometallics 18
- Organoboron chemistry for enantioselective transformations 11.12.2013 -
Lecture Stoechiometric Organometallics 19
- Metal-specific features: Organotitanium Chemistry 17.12.2013 -
Lecture Stoechiometric Organometallics 20
- Metal-specific features: Silicon in Organic Synthesis 18.12.2013 -
Lecture Stoechiometric Organometallics 21
- Single electron transfer processes induced by transition metal salts 14.01.2014 -
Lecture Stoechiometric Organometallics 22
- Transition metal carbonyl complexes in organic synthesis 15.01.2014